Styrene acrylonitrile food safety. Although it is possible that these compounds migrate from .
● Styrene acrylonitrile food safety ABS plastic is known for its strength, durability, and ability to be molded into various shapes and sizes. Gordon L. Styrene is most frequently reported in polymeric components of toys and clothing [41]. Plastics for food packaging and frames for eye glasses are also made from butadiene. 5%]), and body and hand sprays (ethylene/propylene/styrene copolymer [0. Revision Date:2024-12-21 Revision Number:1 (iv) Acrylonitrile/styrene copolymer - no restrictions. Acrylonitrile 05-2117149456-38-0000 01-2119474195-34-0045 Styrene 05-2117149462-45-0000 Manufacturer Product number Product description CAS number Packaging Price Updated Buy; Sigma-Aldrich: 182869: Poly(styrene-co-acrylonitrile) average Mw ~185,000 by GPC, acrylonitrile 30 wt. PS is one of the world's most widely used plastics and >15 Mt of general-purpose high-impact (GP–HI) PS were consumed worldwide in 2015, largely in injection-molded and extruded packaging. ABS is a food-grade into air or food (ATSDR 1990). Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Materials and articles made of acrylonitrile–butadiene–styrene (ABS) intended for contact with food must comply with the requirements of the European Plastic Regulation (EU) 10/2011, which lays down Materials and articles made of acrylonitrile–butadiene–styrene (ABS) intended for contact with food must comply with the requirements of the European Plastic Regulation (EU) 10/2011, which Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 06/30/2015 CAS # Hazardous Components (Chemical Name) NTP 11. , Washington, DC 20204, and the American Society for Testing Materials, 1916 Race Street, Philadelphia, PA Materials and articles made of acrylonitrile–butadiene–styrene (ABS) intended for contact with food must comply with the requirements of the European Plastic Regulation (EU) 10/2011, which lays down the food simulants and the time/temperature conditions to be applied for migration testing. It is widely used in place of polystyrene owing to its greater thermal resistance. Developed in the 1940s, this copolymer has become a cornerstone in the plastics industry, offering a unique blend of properties that make it indispensable in various applications. 3307 S. Acrylonitrile has been detected in food which has been stored in containers manufactured from plastics constructed with acrylonitrile, such as ABS (acrylonitrilebutadiene-styrene), however, the Acrylonitrile/styrene copolymer consisting of the copolymer produced by polymerization of 45-65 parts by weight of acrylonitrile and 35-55 parts by weight of styrene; Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), 5001 Campus Dr. Thanks to its proven ability to styrene-based products today. like bike helmets and safety seats [39], and acrylonitrile-butadiene styrene (ABS) used to make plastic building bricks [40]. Consumer Product Safety Commission frees 7 plastic materials from testing for phthalates in children’s products because they are unlikely to contain the substances polypropylene (PP), 2) polyethylene (PE), 3) high impact polystyrene (HIPS), 4) acrylonitrile butadiene styrene (ABS), 5) crystal and general-purpose polystyrene (GPPS, or Styrene and acrylonitrile monomers can be copolymerized to form a random, amorphous copolymer that has good weatherability, stress crack resistance, and barrier properties. Dust is not expected to be generated in the event of a fire. Workplace Exposure: In workplaces where styrene is used, safety measures are put in place to limit exposure. It is a simple random copolymer. Although some polystyrene (EPS) and acrylonitrile butadiene-styrene (ABS) resins, styrene-acrylonitrile (SAN) fluorocarbons) blowing agents. In this study, the residual styrene levels in high-impact Styrene has been measured in outdoor air, but higher levels generally are found in indoor air, drinking water, groundwater, surface water, soil, and food. ) CAS# 009003-56-9 CAS# 008042-47-5 taste contamination of the food. SECTION 10: Stability and reactivity . If the object is fully covered in a food safe lacquer, then it is food safe, regardless of what lies Acrylonitrile/styrene copolymer modified with butadiene/styrene elastomer identified in this section may be safely used as a component of bottles intended for use with foods identified in table I of § 176. It is not an official It stands for Styrene Acrylonitrile resin, which is a copolymer of acrylonitrile and styrene, and has a large variety of end uses. An official website of the United States government. Other performance properties include UV stability and chemical and heat resistance. The SAN copolymer generally contains 70–80% styrene and 20–30% acrylonitrile. Additionally, isobutylene/styrene copolymer is used in face powders at a maximum concentration of 1%. When used in food-related applications, such as kitchen appliances and food storage containers, ABS plastic is designed to withstand the rigors of daily use without leaching harmful chemicals into food. %, pellets; CAS Number: 9003-54-7; Linear Formula: [CH2CH(C6H5)]x[CH2CH(CN)]y at Sigma-Aldrich. 1050 Acrylonitrile/styrene copoly-mer modified with butadiene/styrene elastomer. Acrylonitrile may potentially be introduced into foodstuffs from acrylonitrile-based polymers used in food packaging. Safety Data Sheet ABS LG5035 Access Date: 5/5/2020 MSDS No. 32 µg dm Food packaging serves purposes of food product safety and easy handling and transport by preventing chemical contamination and enhancing shelf life, which provides convenience for consumers. Copies are available from the Center for Food Safety and Applied Nu-trition (HFS–200), Food and Drug Ad-ministration, 5100 Paint Branch Pkwy. Acrylonitrile (sometimes referred to by its synonym vinyl cyanide, especially by those who seek to raise fears about the safety of the polymer as a food contact material since the monomer is carcinogenic), can be copolymerized with styrene in a ratio of Acrylonitrile Butadiene Styrene (ABS) is a common thermoplastic polymer with various uses, including in kitchenware and food packaging. Production. g. (2000) reported that the average identified level of styrene monomers in food packaging is 100 The migration of acrylonitrile A headspace gas chromatography/mass spectrometry method was developed for the simultaneous determination of the residual levels of acrylonitrile, 1,3-butadiene, and their related compounds containing propionitrile and 4-vinyl-1-cyclohexene in acry Lonitrile- butadiene-styrene copolymers for kitchen utensils and children's toys. , College Park, MD 20740, or available for Food may become acrylonitrile contaminated as a result of monomer migration from acrylonitrile polymer based chemical containers. Acrylonitrile is used as a co-monomer the production of acrylonitrile, butadiene, styrene (ABS) and styrene acrylonitrile (SAN) polymers, which accounts for an additional 31% of use. These food processors and food choppers are made from safer plastics like Acrylonitrile butadiene styrene (ABS) and/or polypropylene (PP) as food contact surfaces. , 2018). Identification Product Name Styrene, stabilized Cat No. It is a lightweight and durable plastic that can be easily molded into various shapes and sizes. Now Trinseo is adding a more environmentally friendly version to our portfolio, the TYRIL™ CO₂NET™ BIO. As raw material suppliers and manufacturers, understanding the features, benefits, and applications of AS plastics can help you better serve your customers and optimize your offerings. Styrene Acrylonitrile (SAN) represents a critical material in our contemporary industrial landscape Acrylonitrile/styrene copolymer consisting of the copolymer produced by polymerization of 45-65 parts by weight of acrylonitrile and 35-55 parts by weight of styrene; Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), 5001 Campus Dr. Plastics are widely used to store and package food and beverages. Polystyrene is one of the most commonly used compounds for packaging of food (Brandsch and Schuster, 2020, Cao et al. 2. Consumer Product Safety Commission in 1978 estimated concentrations of acrylonitrile as less than 1 ppm in acrylic and modacrylic fibers, 30 to 50 ppm in acetonitrile-butadiene-styrene copolymers, 15 ppm in styrene-acrylonitrile copolymers, and 0 to 750 ppm in nitrile rubber and latex goods . And many of these products offer electronics, industrial, food and medical. Application of ABS resins in food contact packaging This scientific opinion of the EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) deals with the safety re-assessment of (butadiene, styrene, methyl methacrylate, butyl acrylate) copolymer cross-linked with divinylbenzene or 1,3-butanediol dimethacrylate for use at up to 40% w/w in blends of styrene acrylonitrile copolymer Acrylonitrile is primarily used in the manufacture of acrylic and modacrylic fibers. Acrylonitrile multipolymers containging indene, methyl methacrylate, and α SAN (Styrene Acrylonitrile) is a copolymer plastic consisting of Acrylonitrile and Styrene. Acrylonitrile/styrene copolymer consisting of the copolymer produced by polymerization of 66-72 Acrylonitrile butadiene styrene (ABS) is a plastic commonly found in household items such as appliances, toys, and even food packaging. 2 Relevant identified uses of the Material Safety Data Sheet or SDS for Acrylonitrile 107-13-1 from chemicalbook for download or viewing in the browser. a. ABS Material Safety Data Sheet 1. It is typically made with 70 to 80% Styrene and 20 to 30% Acrylonitrile. 5 mL or 180 mg/2 mL solution) with closed system transfer devices (CSTD), adapters, and syringes (b) Limitations for acrylonitrile monomer extraction for finished food-contact articles, determined by using the method of analysis titled “Gas-Solid Chromatographic Procedure for Determining Acrylonitrile Monomer in Acrylonitrile-Containing Polymers and Food-Simulating Solvents,” which is incorporated by reference. 1 Reactivity . stress cracking and crazing, easily processed and resistant to This scientific opinion of the EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) deals with the safety re-assessment of (butadiene, styrene, methyl methacrylate $\begingroup$ From what I have seen, you really can't assume a 3d printed part will be food safe when it comes off the printer, even if you are using a food safe filament. Contact: Hazardous Substances Assessment Unit Production of acrylonitrile-butadiene-styrene (ABS) and styrene-acrylonitrile (SAN) plastics, used in automotive parts, household appliances, pipe fittings, containers for food, etc. 70% styrene and 30% acrylonitrile. The chains of between 70 and 80% by weight styrene and 20 to Safety Data Sheet. It offers superior mechanical properties, che mical resistance and h eat resistance in comparison excellent hygiene, sanitation, and safety benefits. In the ongoing discussion about applicable methods to demonstrate compliance, testing with food instead of simulants or total transfer calculations has been proposed. Also, the food characteristics such as fat content, pH, etc. This plastic is petroleum-based and is generally safe in its solid form, releasing no known carcinogens and being used throughout food processing • SAN or Styrene-acrylonitrile resin is a copolymer plastic consisting of styrene and acrylonitrile. Sec. , Suite 900 Emergency Contact: ChemTrec: (800) 424-9300 Information: 1-800-25-RESIN Web site address: www When it comes to food safety, it’s best to play it safe. can significantly affect styrene migration. Acrylonitrile/styrene copolymer consisting of the copolymer produced by polymerization of 45-65 parts by weight of acrylonitrile and 35-55 parts by weight of styrene; Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), 5001 Campus Dr. Trinseo’s styrene acrylonitrile (SAN) monomer polymers are strong, transparent engineering thermoplastics. It is a simple random Substances Assessment Unit of the Health and Safety Authority. Copolymers of acrylonitrile and methly acrylate and terpolymers of acrylonitrile, styrene, and methyl methacrylate are used as barrier polymers. Inhalation termination of Residual Acrylonitrile and Styrene Monomers-Gas Chromatographic Internal Standard Method,’’ which is incorporated by ref-erence. Mcdonald}, journal={Journal of Introduction. , 1983; US National Institute for Occupational Safety and Health, 1983). Foods most likely to contain measureable The safety of ABS (Acrylonitrile Butadiene Styrene) plastic can be considered somewhat controversial. The copolymer is called styrene–acrylonitrile or SAN copolymer. It is still within the safe limits set by regulatory agencies such as the FDA and the European Food Safety Authority. 2/ENG . Consumer Product Safety Commission in 1978 estimated concentrations of acrylonitrile as less than 1 ppm in acrylic and modacrylic fibers, 30 to 50 ppm in acetoni-trile-butadiene-styrene copolymers, 15 ppm in styrene-acrylonitrile copolymers, and 0 to 750 ppm in nitrile rubber and latex goods (as GPS Safety Summary Styrene Monomer 08 March 2019 Page 1 of 5 Global Product Strategy (GPS) Safety Summary polystyrene (EPS) and acrylonitrile butadiene-styrene (ABS) resins, styrene-acrylonitrile (SAN) fluorocarbons) blowing agents. What is SAN? Common applications include food processor bowls, salad crispers in refrigerators, However, the global challenges related to food safety suggest that the current scientific knowledge demonstrates a limited detailed understanding of all the possible materials in a packaging type. Obviously this is very confusing to consumers who are trying to find safe plastics. Residual levels of 14 volatile substances, including 1,3-butadiene, acrylonitrile, benzene, ethylbenzene, and styrene, in 30 kitchen utensils made from acrylonitrile–butadiene–styrene resin (ABS) and acrylonitrile–styrene resin (AS) such as slicers, picks, cups, and lunch boxes in Japan were simultaneously determined using headspace gas chromatography/mass spectroscopy Styrene acrylonitrile resin (SAN) is a copolymer plastic consisting of styrene and acrylonitrile. Isn't it odd to be pouring almost boiling water on a plastic resisting only 90 degrees? Acrylonitrile and styrene-acrylonitrile are two different compounds. These resins mainly compete with plastic resins like polystyrene, acrylics, and polyvinyl chloride when it comes to their machining and wide utility. , College Park, MD 20740, and the American Society for Testing Materials, SAN resins themslaves appear to pose few health problems, and they have been approved by the FDA for direct food contact. This information is pertinent to the safe handling of ABS (Acrylonitrile-Butadiene-Styrene) plastic sheet, and alerts the user to possible health hazards related to its processing. On October 14, 2020, the European Food Safety Authority’s (EFSA) Panel on Food Contact Materials, Enzymes and Processing Aids (CEP) published an assessment on the safety of styrene (CAS 100-42-5) for use in plastic food contact materials (FCMs). Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Campus Dr §177. E. ABS Sheet and Film . Styrene Butadiene Rubber (SBR), which reduces dependence on natural rubbers and provides improved performance in applications such as vehicle tires (leading to improved fuel efficiency), conveyor belts, gaskets, and seals. Lawndale Ave Chicago, IL - 60623 Emergency Contact Phone Number: (815) 221-6400 Food Contact; All Position Statements. acplasticsinc. ABS stands for Acrylonitrile Butadiene Styrene, a type of thermoplastic known for its durability and resistance to impact. Carcinogenicity/Other Information: IARC ACGIH OSHA NA NONE n. The IARC Monograph pertains to This scientific opinion of the EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) deals with the safety re-assessment of (butadiene, styrene, methyl methacrylate, butyl acrylate) copolymer cross-linked with divinylbenzene or 1,3-butanediol dimethacrylate for use at up to 40% w/w in blends of styrene acrylonitrile copolymer Abstract. 4. At the following Styrene is an extremely important commodity chemical used extensively in the manufacture of numerous polymers and copolymers, including polystyrene, acrylonitrile-butadiene-styrene (ABS), styrene-acrylonitrile (SAN), styrene-butadiene latex, and styrene-butadiene rubber. It is often used in place of polystyrene because it provides higher strength, rigidity, and chemical resistance than polystyrene. 4175 www. (i) Acrylonitrile/butadiene copolymer blended with polyvinyl chloride resins - for use only on paper and paperboard in contact with meats and lard. Styrene Acrylonitrile resin, commonly shortened to SAN, is a copolymer of styrene and acrylonitrile, widely used in place of polystyrene owing to its greater thermal resistance. Styrene is released into the air from some industrial facilities, including plastics and fiberglass manufacturers, and waste disposal sites. Styrene has been used for over 70 years to create products which transform our quality of life. (a) Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), 5001 Campus Dr. Robertson, in Reference Module in Food Science, 2019 Acrylonitriles. 3 Possibility of hazardous reactions No hazardous reactions known. Although it is possible that these compounds migrate from Understanding the potential for exposure to styrene is key to evaluating human health risk. 1045 Acrylonitrile. Although styrene monomer is considered as a non-toxic compound, its migration The EFSA Panel on Food Contact Materials, Enzymes and Processing Aids (CEP) was requested by the European Commission to re-evaluate the safety of styrene (FCM No 193) for use in plastic food The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government. A headspace gas Plastim!Ltd!. Styrene is a component of ci In October 1988, the National Institute for Occupational Safety and Health (NIOSH) found insufficient evidence to classify Styrene as a Carcinogen. ABS plastic, or acrylonitrile butadiene styrene, is a widely used thermoplastic polymer known Materials and articles made of acrylonitrile–butadiene–styrene (ABS) intended for contact with food must comply with the requirements of the European Plastic Regulation (EU) 10/2011, which lays down the food ABS (Acrylonitrile Butadiene Styrene) is a common thermoplastic polymer that is widely used in many products and industries. 231. %, powder ABS plastic is a thermoplastic polymer made by the polymerization of acrylonitrile, butadiene, and styrene. 4 Special protective equipment for fire-fighters: Use self-contained breathing apparatus. Stay Organized with Food Kitchen Storage U. There is negligible risk from exposures to styrene through everyday use of consumer products. • Nalgene and Camelbak brand water bottles are #7 BPA-free co-polyester. Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Campus Dr. This bulletin should be read by management and supervisory people who are responsible for safe and ABS (acrylonitrile-butadlene-styrene) is a low-cost engineering thermoplastic that is easily machined, fabricated and thermoformed. SAN is widely used instead of Polystyrene due to its superior thermal resistance. , College Park, MD 20740, and the American Society for Testing Materials, 100 Styrene Acrylonitrile (SAN) plastic: used for food containers, tableware, bathroom fittings, and optical fibers. 177. The U. (1) Nitrogen content of the copolymer is in the range of 16 to 18. That’s great news because lactic acid is completely harmless and, in This scientific opinion of the EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) deals with the safety re-assessment of (butadiene, styrene, methyl methacrylate, butyl acrylate) One of the main concerns regarding food packaging safety is the possible migration of unwanted chemicals, such as monomers and additives, from the packaging where the concentration of acrylonitrile monomer migrated from ABS pellets, and styrene–acrylonitrile copolymer in water and ethanol (10% v/v) was between 0. Also, Tang et al. Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Campus unsaturated polyester/epoxy vinylester/styrene polymers for food containers (vats, other large vessels) in industrial applications; (EC) concerning the safety of styrene in FCMs 1. Advancements in SAN Technology and the incorporation of flame retardants to enhance safety. The Electronic Code of Federal Regulations (eCFR) is a continuously updated online version of the CFR. (1,6) Sources and Potential Exposure This scientific opinion of the EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) deals with the safety re-assessment of (butadiene, styrene, methyl methacrylate, butyl acrylate) copolymer cross-linked with divinylbenzene or 1,3-butanediol dimethacrylate for use at up to 40% w/w in blends of styrene acrylonitrile copolymer Styrene is associated with increased risk of leukemia and lymphoma, and can be found in air, water, and soil. , and Styrene acrylonitrile (SAN) belongs to the family of styrene copolymers. 170(c) of this chapter Glass Transition Temperature The glass transition is one of the most important properties of amorphous and semi-crystalline materials, e. 800. Lickly and Dan A. When it comes to food safety, it is important to consider the materials used in food containers and packaging. Styrene is a VOC that is a neurotoxicant [42, 43] and a probable human carcinogen [44, 45]. Three SAN (Styrene Share this article: Acrylonitrile Styrene (AS) plastics have gained significant traction in various industries due to their unique properties and versatility. Number 7 plastics are used for a variety of products like baby bottles and “sippy” cups, baby food jars, 5-gallon water bottles, “sport” water bottles, plastic dinnerware and clear plastic cutlery. The Safety Data Sheet (SDS) SDS‐102‐Acrylonitrile‐Butadiene‐Styrene Hoehn Plastics, Inc. Here is how you know (styrene/acrylates copolymer [3. ABS/SAN resins are used in construction materials, appliances, business machines GPS Safety Summary Styrene Monomer 08 March 2019 Page 3 of 5 Styrene and acrylonitrile monomers can be copolymerized to form a random, amorphous copolymer that has good weatherability, stress crack resistance, and barrier properties. As far as I know, the current literature on the food-safety of plastic materials suggests that even food-grade plastic leaches chemicals, especially at high temperatures. Do not store near heating devices, hot pipes, etc. It is primarily used in food packaging, insulation and cushion packaging. Because styrene/acrylates copolymer, styrene/VP copolymer, and ethylene/propylene/styrene copolymer are used in products (c) Specifications. 1. (2) Residual acrylonitrile monomer content of the finished copolymer articles is not more than 11 parts per million as determined by a gas chromatographic method titled "Determination of Residual Acrylonitrile and Styrene Monomers ABS stands for acrylonitrile butadiene styrene, which are the three main components of this plastic. The monomer is often copolymerized with other monomers or the polymer is blended with other plastics to improve its properties such as flexibility SAFETY DATA SHEET Acrylonitrile Butadiene Styrene Revision date: 08 -11 -2023 Version: 1. Sustainability. 02 and 2. , College Park, MD 20740, and the American Society for Testing Materials To quantify the risk of an adverse health effect from chemical exposure to styrene and acrylonitrile, information on the chemical hazard and exposure level need to be available (Food Packaging and Health, 2021). ABS is also known as nitrile rubber or NBR. §177. Below are some of the characteristics of SAN plastic. These polymers are used in a wide range of oil- and chemical-resistant nitrile rubber for industrial hoses, gaskets and seals. ABS can potentially release its constituent chemicals, such as styrene, particularly when exposed to high temperatures, fatty, or acidic foods. Exposure index values in SAN, electrical, and instrumentation units, facilities, and mechanics are 0 The safety of materials in polymers is very important (Guart et al. , College Park, MD 20740, or available for inspection at the National Archives and Records Administration (NARA). , 2015). SAN (styrene acrylonitrile) plastic is a type of plastic that generally contains around 70% styrene and 30% acrylonitrile. Use water spray to keep fire-exposed containers cool. This product is not classified as environmentally hazardous. Styrene can be emitted to the air from industrial production and use of styrene and styrene-based polymers and copolymers, motor-vehicle emissions and other combustion processes, offgassing Styrene is used to produce polystyrene, ABS (Acrylonitrile Butadiene Styrene), unsaturated polyester, latex and synthetic rubber, which are used in a number of applications including injection molding, disposables, food packaging, housewares, paints and coatings, resins, building materials and toys. : AC132790000; AC132790010; AC132790025; AC132790050; CAS No 100-42-5 Synonyms Ethenylbenzene Recommended Use Laboratory chemicals. Because styrene/acrylates copolymer, styrene/VP copolymer, and ethylene/propylene/styrene copolymer are used in products STYRENE IN CONSUMER PRODUCTS Consumer products made with styrene remain safe. Styrene is a high production chemical; the production capacity for styrene in the United States was over 12 billion pounds in 2008. Section 4 First-Aid Measures Inhalation Remove affected individual to fresh air, seek medical attention if difficulties in Production of acrylonitrile-butadiene-styrene (ABS) and styrene-acrylonitrile (SAN) plastics Monomer for production of nitrile rubbers Acrylonitrile SAFETY DATA SHEET Date of revision : 3 May 2021 Page : 2 of 141 Version 11. General Measures If safe to do so, move undamaged containers from fire area. What is Styrene Acrylonitrile Resin? Styrene Acrylonitrile Resin, commonly known as SAN resin, is a type of copolymer. 6 Food. Previous studies indicated that high concentrations of ethanol at Acrylonitrile butadiene styrene, also known as ABS plastic, is a heat- and impact-resistant lightweight material that can be used to make materials for toys like building blocks, as well as musical instruments like clarinets and recorders. Styrene is produced mainly by catalytic dehydrogenation of high-purity Styrene acrylonitrile | C11H11N | CID 62696 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. SECTION 6: ACCIDENTAL RELEASE The European Food Safety Authority is re-evaluating styrene for assessing the safety of food contact materials (FCM) such as polystyrene (PS) and started a systematic review of the data on This guide provides a chemical compatibility table for Styrene-Acrylonitrile, based on data (at 20°C) from DWK Life Sciences, to help users evaluate its suitability for specific needs. Uses advised against Food, drug, pesticide or [03/10/2015] FDA is warning health care professionals not to use Treanda Injection (45 mg/0. From the time each of us awakes in the morning to the time we go to bed, styrene-based products are adding convenience, comfort, and safety our lives. After safety and firefighting units, the highest concentration of acrylonitrile vapors is present in styrene acrylonitrile (SAN) units, electrical and instrumentation, installations, and mechanics with 155, 140, 69, and 41 μg/m 3, respectively. Although it’s an old study, research into the safety of PLA as a food container revealed that the only thing likely to leak into the contents was lactic acid. 1050 Acrylonitrile/styrene copoly- mer modified with butadiene/sty-rene elastomer. acrylonitrile-butadiene-styrene, and A precautionary specific migration limit of 40 µg/kg for styrene from food contact materials is currently under evaluation in Europe. Food Safety of ABS Plastic. In 2019 SIRC completed a comprehensive assessment of styrene exposure to add to the body of knowledge of styrene. Styrene is used in polystyrene, polyamide, and acrylonitrile–butadiene–styrene (Chung et al. Small amounts of styrene are naturally present in foods such as legumes, beef, clams, eggs, nectarines, and spices. It can also be present in packaged foods by migration from polystyrene food containers and packaging materials. The copolymer is called styrene-acrylonitrile or SAN. However, other compositions are also possible and have an impact on the material properties such as Glass Transition Temperature The glass transition is one of the most important properties of amorphous and semi-crystalline materials, SAFETY DATA SHEET Creation Date 09-May-2012 Revision Date 23-Aug-2022 Revision Number 6 1. Manufacturer: Star Plastics, Inc. S. Food and Drug Administration (FDA) for use in food-related applications, including food packaging, kitchen utensils, and appliances. According to reports, styrene and acrylonitrile are considerably present in ABS toys, with maximum content levels reaching 2600 mg/kg and 55 Food packaging serves purposes of food product safety and easy handling and transport by preventing chemical contamination and enhancing shelf life, which provides convenience for consumers. To ensure food safety, allowable levels of some of these volatile substances in food contact materials are regulated around the world. Acrylonitrile/styrene copolymer modified with butadiene/styrene elas-tomer identified in this section may be safely used as a component of bottles intended for use with foods identified in table I of §176. (1,6) Sources and Potential Exposure SAN (Styrene Acrylonitrile) is a copolymer of styrene and acrylonitrile. 10. , 2013, Marć et al. Toxicological Information Toxicological Information: No data available. Poly(styrene-co-acrylonitrile) average Mw ~165,000 by GPC, acrylonitrile 25 wt. In this study, composite food samples from a recent (2014) Canadian Total Diet Study Styrene-Acrylonitrile (SAN), also known as Acrylonitrile Styrene (AS), represents a significant milestone in the evolution of synthetic polymers. acrylonitrile-butadiene-styrene (ABS) and SAN to be used for the fatty and aqueous based foods. Commercial production of styrene via dehydrogenation of ethylbenzene began in Germany in 1925 (Tossavainen, 1978; Lewis et al. 100-42-5) is an important high production volume chemical used primarily as an intermediate in the production of a number of commercially important polymers and copolymers that are in turn used to make a wide variety of products of industrial, consumer, and medical importance, including polystyrene (building Plastic marked with a #7 recycling symbol—signifying mixed sources (polycarbonate) or otherwise hard-to-classify plastics (such as acrylonitrile styrene or acrylonitrile butadiene styrene)—is SAFETY DATA SHEET ACRYLONITRILE STYRENE ACRYLATE (ASA) REVISION 3, DATE 14 SEP 2020 Form 21047, Revision 3, Page 2 of 9, 11-Nov-2024 02:04:51. Uses of these polymers include fibres for clothing, carpets , and other textiles , as well as plastics for consumer products, automotive parts, and construction. Styrene (C6H5CH = CH2, CAS No. This copolymer is composed of styrene and acrylonitrile in varying proportions, typically ranging from 70 to 80% styrene and 20 to 30% acrylonitrile. (2) Coatings. For those who strive to buy polymers online with complete safety and ease Acrylonitrile Butadiene Styrene, or ABS, is a type of thermoplastic polymer that is widely used in a variety of applications, including automotive parts, Ultimately, the best way to ensure the safety of your food and your health is to choose non-plastic options for food storage and cooking whenever possible. However, concerns have arisen about the safety of ABS plastic when it comes into contact with food. Proper use and care. , College Park, MD 20740, and the American Society for Testing Materials ABS (Acrylonitrile Butadiene Styrene) is a common type of plastic used in various industries, including the production of food containers and utensils. Styrene–acrylonitrile (SAN) is a copolymer of styrene with acrylonitrile, and SMA, a copolymer with small amounts of maleic anhydride. Acrylonitrile. 5. n. accounts for 15% of use, while a Styrene-maleic anhydride copolymers identified in paragraph (a) of this section may be safely used as articles or components of articles intended for use in contact with food, subject to provisions of this section. 5%]). Styrene is a Materials and articles made of acrylonitrile–butadiene–styrene (ABS) intended for contact with food must comply with the requirements of the European Plastic Regulation (EU) 10/2011, which SAN resins themslaves appear to pose few health problems, and they have been approved by the FDA for direct food contact. , inorganic glasses, amorphous metals, polymers, pharmaceuticals and food ingredients, etc. However, its food safety depends on several factors. By being aware of the potential Acrylonitrile is primarily used in the manufacture of acrylic and modacrylic fibers. • BPA-free acrylic plastic dinnerware is also #7. Styrene was first isolated in 1831 by distillation of storax, a natural balsam. – Poseyville, IN Page 1 of 3 SECTION 1: PRODUCT AND COMPANY INFORMATION Hoehn Plastics Inc. Styrene has shaped and enhanced our daily lives for many years. Exposure to styrene occurs in workplaces that manufacture styrene or use styrene to produce important polymers and co-polymers of industrial, consumer, and PRODUCT SAFETY BULLETIN Styrene Monomer - LyondellBasell EN English Deutsch Français Español Português Italiano Român Nederlands Latina Dansk Svenska Norsk Magyar Bahasa Indonesia Türkçe Suomi Latvian Lithuanian český русский български العربية Unknown Styrene-acrylonitrile-copolymer (SAN) and acrylonitrile-butadiene-styrene-copolymer (ABS) are gaining in importance as food contact materials. The input consists of catering tableware food contact articles from airline on‐board services, made of polypropylene (PP), polyethylene terephthalate (PET), styrene acrylonitrile resin (SAN) or Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Campus Dr. 2 Chemical stability Stable under normal conditions of storage and use. Design teams working in the food and beverage industries should know what the best food-safe plastic materials are to ensure products remain safe for consumers. It has been approved by regulatory bodies such as the U. The IARC DOI: 10. 326 Jack Burlingame Drive Safety Data Sheet Acrylonitrile-Butadiene-Styrene Copolymer (ABS) According to EU 2015/830 (REACH) and 1272/2008 (CLP) Product name: ABS Version 1 Revision Date: June 1,2015 Page 2 of 10 Pre-registration No. 0/ENG Revision date: 09-01-2020 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1. 7. They offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. All MSDS PDF. Acrylonitrile/styrene copolymers identified in this section may be safely Copies are available from the Center for Food Safety and Applied Nutrition (HFS–200), 200 C Street SW. , 2020). 6. 70% of which is used Bonding SAN (Styrene-Acrylonitrile) Laurie Gibbons Bonding Plastic, Material Specific Adhesives July 23, 2015. Chemical Safety Data Sheet MSDS / SDS. Acrylonitrile, styrene, and ethylbenzene, which were detected in the above described migration tests, are classified as group 2B carcinogens by IARC. , 11481 West, County Road 925 South, Poseyville, IN 47633 (812) 874‐2612 Product Family: Polymer The EFSA Panel on Food Contact Materials, Enzymes and Processing Aids (CEP) assessed the safety of the recycling process deSter (EU register number RECYC196). Registration No. The answer is YES, ABS is generally considered safe for food contact. With automotive, engineering, etc. It’s considered a food-grade thermoplastic and can be safe for use in food processing. The chemical compound is considered safe for human consumption, but some consumers are concerned about its safety. DOES STYRENE CAUSE CANCER? There are no strong or consistent indications that styrene causes any form of cancer in humans. 1040 Acrylonitrile/styrene copoly-mer. , College Park, MD 20740, and the American Society for Testing Materials styrene-containing plastics – high-impact polystyrene (hips) and acrylonitrile-butadiene-styrene (abs) Polystyrene is a rigid, brittle and inexpensive plastic sometimes used to make plastic toys. Fortunately, checking plastic labels for food safety is a straightforward process, and it all comes down to understanding the Safety Data Sheet (SDS) SDS-800- Acrylonitrile-Butadiene-Styrene (ABS) Section 1: Identification Product Name: SATRAN Acrylonitrile-Butadiene-Styrene (ABS) Product Series: 800, 800R, 805, 800GF10, 800GF20, 800HG, 800HH Company Name: MRC Polymers Inc. SAN is labeled #7. Occupational Safety and Health Administration (OSHA) has specific engineering safeguards outlined for this chemical, as stated in OSHA standard 29 CFR 1910. ChemicalBook. ABS/SAN resins are used in 1. The Commission provided feedback on their intention to follow up the assessment made by EFSA 3 and to set a specific migration limit (SML)”. ABS is an amorphous plastic created by combining acrylonitrile, butadiene, and styrene polymers. One such material that has gained popularity in recent years is ABS plastic. Styrene is found in tobacco smoke. 1021/JF00025A026 Corpus ID: 98226652; Migration of acrylonitrile from styrene/acrylonitrile copolymers into food-simulating liquids @article{Lickly1993MigrationOA, title={Migration of acrylonitrile from styrene/acrylonitrile copolymers into food-simulating liquids}, author={Tim D. This thermoplastic material has excellent chemical, stress and creep resistance. Food containers Acrylonitrile/styrene copolymers identified in this section may be safely used as a component of packaging materials subject to the provisions of this section. 1 Product identifier Trade name: ABS Substance name: Recycled Acrylonitrile-Butadiene-Styrene Copolymer (ABS) 1. 5 percent as determined by Micro-Kjeldahl analysis. 4 Emergency Acrylonitrile/styrene copolymer consisting of the copolymer produced by polymerization of 45-65 parts by weight of acrylonitrile and 35-55 parts by weight of styrene; Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), 5001 Campus Dr. Acrylonitrile multipolymers containging indene, methyl methacrylate, and α The International Chemical Safety Card on acrylonitrile (ICSC 0092), produced by the International Programme on Chemical Safety (IPCS, 1993), has also been reproduced in this document. limitation. The EFSA Panel on Food Contact Materials, Enzymes and Processing Aids (CEP) was requested by the European Commission to re‐evaluate the safety of styrene (FCM No 193) for use in plastic food contact materials (FCM) following the classification by the International Agency for Research on Cancer (IARC) as ‘probably carcinogenic to humans’. ABS offers a good balance of History of Food Packaging. We have the capacity to produce high-purity styrene monomer that is (styrene/acrylates copolymer [3. [1, 2] Despite its known health hazards, companies continue to produce styrene to make plastics and rubber with end uses in packaging, building materials like insulation, and food-contact items. Markham and M. Refer to this table to make informed choices and maintain the The EFSA Panel on Food Contact Materials, Enzymes and Processing Aids (CEP) was requested by the European Commission to re-evaluate the safety of styrene (FCM No 193) for use in plastic food contact materials (FCM) following the classification by the International Agency for Research on Cancer (IARC) as ‘probably carcinogenic to humans’. This may include the use of personal protective equipment Choose from various types of containers like food storage canisters, food storage container sets, reusable food storage bags and food storage bottles. It is also used as a raw material in the manufacture of plastics (acrylonitrile-butadiene-styrene and styrene-acrylonitrile resins), adiponitrile, acrylamide, and nitrile rubbers and barrier resins. They are commonly injection molded or shaped via extrusion. Sustainability Home; Health And Safety; Styrene Acrylonitrile copolymers have been available since the 1940’s and while its increased toughness over styrene made it suitable for ABS plastic is considered food safe by the Food and Drug Administration (FDA) in the United States and regulatory bodies in other countries. Styrene-acrylonitrile Resin (SAN): Another significant use of styrene is in SAN resin, used for producing rigid plastic products such as food containers and optical fibers. co Trinseo’s TYRIL styrene acrylonitrile (SAN) monomer polymers are strong, transparent engineering thermoplastics that offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. 0 1. Use a food safe lacquer, or some other food safe coating. !Unit!100,!Ashville!Business!Park,!Commerce!Road,!Staverton,!Gloucestershire,!GL2!9QJ! Tel:!+44(01452)!857733!!Fax:!+44(01452)!857744!! sales@plastim. The best part of this answer is the final paragraph. Stable under normal conditions of storage and use. com Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. Safety An extensive UK survey of styrene monomer levels in styrene based plastic packaging materials and their contained foods has been carried out, examining a wide range of retail foods including yogurts, creams, salads, coleslaws, soft cheeses, margarines, hot and cold beverages from dispensing machines, spreads, fresh and cooked meats, candied fruits, fresh strawberries, and Hydrogen Cyanide, Styrene, Ethylbenzene and Acrylonitrile may be emitted. Conclusion. A typical composition is approx. The CEP was requested by the European Commission (EC) to complete the assessment following a 2018 conclusion by the polyamide and plastic mixtures like styrene-acrylo-nitrile resin (SAN). Braun 8-cup Food Processor Costway Food Processor Low levels of styrene may be found in foods as a result of possible migration from polystyrene-based food packaging and as a result of its formation during the biodegradation of a wide variety of naturally occurring compounds with structures similar to styrene. These food storage containers are space saving and come in compact designs for perfect organization and stacking in your fridge or cabinet. [1] Acrylonitrile-Butadiene-Styrene Copolymer Version: 1. polyacrylonitrile, styrene–acrylonitrile, acrylonitrile butadiene styrene, and other synthetic rubbers such as acrylonitrile butadiene. Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 09/17/2015 Product Name: Styrene Acrylonitrile Resin Trade Name: Certene Company Name: Muehlstein Ravago Manufacturing Americas Orlando, FL 32810 1900 Summit Tower Blvd. Exposure to acrylonitrile Cyano substituent is also included in some styrene copolymers such as styrene-acrylonitrile (SAN), acrylonitrile styrene acrylate (ASA), and acrylonitrile butadiene styrene (ABS), a widely used group of thermoplastics to produce light, rigid, molded materials for toys, safety helmets, electronics, automobile bumps, and building construction Copies are available from the Center for Food Safety and Applied Nutrition (HFS-200), Food and Drug Administration, 5001 Campus Dr. ABS 984001 Page 1 Product Identifier: ABS Chemical Formula: Acrylonitrile, Butadiene, Styrene General Product Use: May be used to produce molded or extruded articles or as a component of other industrial products. However, there has been some debate surrounding its safety when it comes into contact with food. Small amounts of styrene can be transferred to some food from polystyrene-based food-contact items, such as drinking cups, plates, and other containers. Key findings and conclusions: The quality of PS packaging material in terms of their styrene monomer residue level and the storage conditions of foods can greatly affect styrene migration. , 2011, Peivasteh-Roudsari et al. Similarly, the US Food and Drug Administration (FDA) has established regulations regarding the use of SAN in food-contact applications. xgzansqtusymrrndtqnoetnaliolwuhodhhhrmehchybvbimcowhh